biology daily - the biology and biochemistry encyclopedia
biology daily articles and research Encyclopedia Dictionary Forums biology research links Weblinks Pictures Articles Blogs Newsletter

Quantum solvent

Any superfluid can theoretically act as a quantum solvent. In practice, the only viable superfluid medium that can be used is helium-4, and it has been successfully accomplished in controlled conditions.

Any inhomogeneity in the bulk superfluid medium will tend to aggregate together, encapsulated by a quantum solvation shell. This consists of a region of non-superfluid helium-4 atoms that surround the molecule(s) and exhibit adiabatic following around the centre of gravity of the whole object. Due to the frictionless nature of the superfluid medium, this quantum solvation shell then proceeds to act very much like a nanoscopic ball bearing, allowing effectively complete rotational freedom of the solvated chemical species. The only caveat to this is the necessity of altering the rotational constant of the species to compensate for the higher mass entailed by the quantum solvation shell.

Quantum solvation has so far been achieved with a number of organic, inorganic and organometallic compounds, and it has been speculated that as well as the obvious use in the field of spectroscopy, quantum solvents could be used as tools in nanoscale chemical engineering, perhaps to manufacture components for use in nanotechnology.



07-14-2008 23:18:10
The contents of this article are licensed from Wikipedia.org under the GNU Free Documentation License. How to see transparent copy
BiologyDaily.com 2005. Legal info   Privacy